Pb5.0(1)In8.4(1)Bi1.6(1)S20, a new quaternary lead indium bismuth sulfide.
Identifieur interne : 000B50 ( Main/Exploration ); précédent : 000B49; suivant : 000B51Pb5.0(1)In8.4(1)Bi1.6(1)S20, a new quaternary lead indium bismuth sulfide.
Auteurs : RBID : pubmed:22382529Abstract
The title phase, first detected in the early 1980s but hitherto unpublished, has been resynthesized and structurally characterized. Unambiguous determination of the chemical composition was not possible by structure analysis alone, but required additional analytical methods. The complex structure shows a close similarity to the structures of two related compounds, one known by the formula Pb(1.6)In(8)Bi(4)S(19) and the other being the ternary compound Pb(6)In(10)S(21). This is despite the fact that the three phases correspond to very different Pb:Bi ratios. A geometric mechanism is described by which the three structures can be transformed into each other, provided that the heavy atoms Pb and Bi are treated as equivalent.
DOI: 10.1107/S0108270112001011
PubMed: 22382529
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Unambiguous determination of the chemical composition was not possible by structure analysis alone, but required additional analytical methods. The complex structure shows a close similarity to the structures of two related compounds, one known by the formula Pb(1.6)In(8)Bi(4)S(19) and the other being the ternary compound Pb(6)In(10)S(21). This is despite the fact that the three phases correspond to very different Pb:Bi ratios. A geometric mechanism is described by which the three structures can be transformed into each other, provided that the heavy atoms Pb and Bi are treated as equivalent.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">22382529</PMID><DateCreated><Year>2012</Year><Month>03</Month><Day>02</Day></DateCreated><DateCompleted><Year>2012</Year><Month>05</Month><Day>16</Day></DateCompleted><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1600-5759</ISSN><JournalIssue CitedMedium="Internet"><Volume>68</Volume><Issue>Pt 3</Issue><PubDate><Year>2012</Year><Month>Mar</Month></PubDate></JournalIssue><Title>Acta crystallographica. Section C, Crystal structure communications</Title><ISOAbbreviation>Acta Crystallogr C</ISOAbbreviation></Journal><ArticleTitle>Pb5.0(1)In8.4(1)Bi1.6(1)S20, a new quaternary lead indium bismuth sulfide.</ArticleTitle><Pagination><MedlinePgn>i12-6</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S0108270112001011</ELocationID><Abstract><AbstractText>The title phase, first detected in the early 1980s but hitherto unpublished, has been resynthesized and structurally characterized. Unambiguous determination of the chemical composition was not possible by structure analysis alone, but required additional analytical methods. The complex structure shows a close similarity to the structures of two related compounds, one known by the formula Pb(1.6)In(8)Bi(4)S(19) and the other being the ternary compound Pb(6)In(10)S(21). This is despite the fact that the three phases correspond to very different Pb:Bi ratios. A geometric mechanism is described by which the three structures can be transformed into each other, provided that the heavy atoms Pb and Bi are treated as equivalent.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Reis</LastName><ForeName>I</ForeName><Initials>I</Initials><Affiliation>Kristallographie, Institut für Geowissenschaften, Albert-Ludwigs-Universität Freiburg, Freiburg, Germany.</Affiliation></Author><Author ValidYN="Y"><LastName>Krämer</LastName><ForeName>V</ForeName><Initials>V</Initials></Author><Author ValidYN="Y"><LastName>Seiler</LastName><ForeName>A</ForeName><Initials>A</Initials></Author><Author ValidYN="Y"><LastName>Topa</LastName><ForeName>D</ForeName><Initials>D</Initials></Author><Author ValidYN="Y"><LastName>Keller</LastName><ForeName>E</ForeName><Initials>E</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2012</Year><Month>02</Month><Day>04</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Acta Crystallogr C</MedlineTA><NlmUniqueID>8305826</NlmUniqueID><ISSNLinking>0108-2701</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2011</Year><Month>10</Month><Day>28</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2012</Year><Month>1</Month><Day>10</Day></PubMedPubDate><PubMedPubDate PubStatus="epublish"><Year>2012</Year><Month>2</Month><Day>04</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2012</Year><Month>3</Month><Day>3</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2012</Year><Month>3</Month><Day>3</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2012</Year><Month>3</Month><Day>3</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pii">S0108270112001011</ArticleId><ArticleId IdType="doi">10.1107/S0108270112001011</ArticleId><ArticleId IdType="pubmed">22382529</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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